Care of webopedia.com:

100BASE-TX: two pairs of high-quality twisted-pair wires 
100BASE-T4: four pairs of normal-quality twisted-pair wires 
100BASE-FX: fiber optic cables 

As for getting it to work, you can specify the media with ifconfig.  I
don't remember the exact syntax off hand but I think it goes something
like:

ifconfig -media 10baseT/UTP


I ran into this with a FreeBSD machine where the 3.x worked but 4.x didn't
like my network card.  Turns out it defaults to the AUI port (which
shows up the in the boot messages... duh) but it had me scratching my head
for a while.


Hope this helps,
Charlie